Hydronium 4-oxo-1,4-dihydropyridine-3-sulfonate dihydrate

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Hydro­nium 4-oxo-1,4-dihydro­pyridine-3-sulfonate dihydrate

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The title compound, (C(10)H(10)N(2))[Sb(2)(C(7)H(2)NO(5))(2)(OH)(2)(H(2)O)(2)]·2H(2)O, consists of a binuclear anion, a diprotonated 4,4'-bipyridinium cation and two uncoordinated water mol-ecules. Each Sb(III) atom is six-coordinated by one chelating 4-oxidopyridine-2,6-dicarboxyl-ate ligand, one water mol-ecule, one OH group and one bridging O atom from a neighboring carboxyl-ate group in a d...

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The title mol-ecule, C(22)H(17)BrN(2)O(4)S, has a twisted U shape, the dihedral angle between the quinazolin-4-one and bromo-benzene ring systems being 46.25 (8)°. In order to avoid steric clashes with adjacent substituents on the quinazolin-4-one ring, the N-bound tolyl group occupies an orthogonal position [dihedral angle = 89.59 (8)°]. In the crystal, mol-ecules are connected into a three-di...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2009

ISSN: 1600-5368

DOI: 10.1107/s1600536809040641